Material Safety Data Sheet
Sodium chlorite, unstabilized, tech., 80%
ACC# 07618
Section 1 - Chemical Product and Company Identification |
MSDS Name: Sodium chlorite, unstabilized, tech., 80%
Catalog Numbers:
AC223230000, AC223230050, AC223235000
Synonyms:
Alicide LD; Chlorous Acid, Sodium SAlt (8CI, 9CI)
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7758-19-2 |
Sodium chlorite |
80 | 231-836-6 |
7647-14-5 |
Sodium chloride |
20 | 231-598-3 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white flakes.
Danger! Strong oxidizer. Contact with other
material may cause a fire. Harmful if swallowed. Causes eye and skin
irritation and possible burns. Causes digestive and respiratory tract
irritation with possible burns. Hygroscopic (absorbs moisture from
the air).
Target Organs: Blood, kidneys, eyes, skin,
mucous membranes.
Potential Health Effects
Eye:
Contact may cause severe eye irritation and possible eye damage.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
May cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). Dust is irritating to the respiratory
tract. May cause respiratory tract irritation.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. Use water with caution and in flooding amounts.
Extinguishing Media:
Use water only! Contact professional fire-fighters immediately.
Flash Point: 180 deg C ( 356.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:7.00 vol %
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0; Special Hazard: OX
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Avoid
generating dusty conditions. Remove all sources of ignition. Provide
ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store in
a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Sodium chlorite
|
none listed
|
none listed
|
none listed
|
Sodium chloride
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Sodium chlorite:
No OSHA Vacated PELs are listed for this chemical.
Sodium chloride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Flakes
Appearance: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 3.1
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:180 deg C
Solubility: 39 g/100ml (17 c)
Specific Gravity/Density:Not available.
Molecular Formula:ClNaO2
Molecular Weight:90.44
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, organic materials.
Incompatibilities with Other Materials:
Strong reducing agents, strong acids, ammonia, finely powdered
metals, phosphorus, zinc.
Hazardous Decomposition Products:
Hydrogen chloride, sodium oxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7758-19-2:
VZ4800000
CAS# 7647-14-5:
VZ4725000
LD50/LC50:
CAS# 7758-19-2:
Inhalation, rat:
LC50 = 230 mg/m3/4H;
Oral, mouse:
LD50 = 350 mg/kg;
Oral, rat: LD50 =
165 mg/kg;
Oral, rat: LD50 = 350
mg/kg;
.
CAS# 7647-14-5:
Draize test,
rabbit, eye: 100 mg Mild;
Draize
test, rabbit, eye: 100 mg/24H Moderate;
Draize test, rabbit, eye: 10 mg
Moderate;
Draize test, rabbit,
skin: 50 mg/24H Mild;
Draize test,
rabbit, skin: 500 mg/24H Mild;
Inhalation, rat: LC50 = >42
gm/m3/1H;
Oral, mouse: LD50 = 4
gm/kg;
Oral, rat: LD50 = 3000
mg/kg;
Skin, rabbit: LD50 = >10
gm/kg;
.
Carcinogenicity:
CAS# 7758-19-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7647-14-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
SODIUM CHLORITE |
SODIUM CHLORITE |
Hazard Class: |
5.1 |
5.1 |
UN Number: |
UN1496 |
UN1496 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7758-19-2 is listed on the TSCA inventory.
CAS# 7647-14-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7758-19-2: immediate, fire, sudden release of pressure.
CAS # 7647-14-5: immediate.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7758-19-2 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
CAS# 7647-14-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+ O
Risk Phrases:
R 25 Toxic if swallowed.
R 9 Explosive when mixed with combustible material.
Safety Phrases:
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# 7758-19-2: 2
CAS# 7647-14-5: 0
Canada - DSL/NDSL
CAS# 7758-19-2 is listed on Canada's DSL List.
CAS# 7647-14-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of C, D1B, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7758-19-2 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 2/24/1999
Revision #3 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.